1222558-91-9Relevant academic research and scientific papers
Suzuki-miyaura cross-coupling reaction in water with polymer-supported terpyridine palladium complex under aerobic conditions
Suzuka, Toshimasa,Nagamine, Takuya,Ogihara, Kazuhito,Higa, Matsutake
, p. 85 - 89 (2010)
A polymer-supported terpyridine Pd(II) complex was prepared and found to promote the Suzuki-Miyaura coupling reaction in water. Thus, terpyridine ligand was prepared from p-hydroxybenzaldehyde, propane sultone, and 2-acetylpyridine according to the reported procedures. Immobilization of terpyridine ligand onto a polystyrene-poly(ethylene glycol) (PS-PEG) resin through ionic bonds to sulfonate group took place and the complexation of PS-PEG-terpyridine ligand with Pd(II) underwent to give PS-PEG-terpyridine-Pd(II) complex. This polymeric catalyst showed high catalytic activity and high reusability for the Suzuki-Miyaura coupling reaction. Graphical Abstract: [Figure not available: see fulltext.]
Reusable polymer-supported terpyridine copper complex for [3+2] Huisgen cycloaddition in water
Suzuka, Toshimasa,Ooshiro, Kazumasa,Kina, Ken'yu
experimental part, p. 601 - 610 (2010/09/07)
A polymer-supported terpyridine copper(I) complex was prepared and found to promote the Huisgen [3+2] cycloaddition reaction between azides and alkynes in water to give the corresponding triazoles with up to 87% isolated yield. This catalyst was recovered
