122270-51-3Relevant academic research and scientific papers
Regio- and stereochemical aspects in the synthesis of homoallylic alcohols from benzoins and their iodocyclisation to 2,3-diphenyltetrahydrofurans
Kumar, Subodh,Kaur, Pervinder,Mittal, Anu,Singh, Palwinder
, p. 4018 - 4026 (2006)
Indium mediated allylation, crotylation and cinnamylation of benzoins and its substituted derivatives in THF-H2O (2/1) provide a range of homoallylic alcohols. In general, the benzoins undergo allylation and crotylation in a sluggish manner com
Diastereoselective Allylation of ω-Hydroxy Caronyl Compounds by Allylic Alcohols with Pd-SnCl2
Takahara, Jun P.,Masuyama, Yoshiro,Kurusu, Yasuhiko
, p. 879 - 882 (2007/10/02)
Allylation of ω-hydroxy carbonyl compounds by allylic alcohols with Pd-SnCl2 proceeded smoothly in neutral polar medium with high regio- and diastereocontrol via chelated bicyclic transition state.
Stereoselective allyl- and crotylboration of alpha-hydroxyketones via neighboring group control
Wang, Zhe,Meng, Xian-Jun,Kabalka, George W.
, p. 1945 - 1948 (2007/10/02)
Allylboronates and crotylboronates react with alpha-hydroxyketones to yield tertiary homoallylic alcohols in a highly stereocontrolled manner. The reaction presumably proceeds via a rigid bicyclic transition state. The alpha-hydroxy substituent exerts a r
