122274-03-7

Upstream product

• 62994-45-0 ((2R,4R)-1,3,3-Trimethyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-methanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 66465-69-8 (2S,4R)-1,3,3-Trimethyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester 
• 72444-99-6 (1S,5S,7R)-6,6-Dimethyl-3-nitroso-10-oxa-3-aza-tricyclo[5.2.1.0^1,5]decan-4-one 
• 72445-04-6 (1S,5S,7R)-6,6-Dimethyl-10-oxa-3-aza-tricyclo[5.2.1.0^1,5]decan-4-one 
• 122273-93-2 trimethyl-1,3,3 pivaloyloxymethyl-2 oxa-7 bicyclo<2.2.1>heptane exo 
• 77704-39-3 (1S,5S,7R)-3-((R)-2-Hydroxy-1-phenyl-ethyl)-6,6-dimethyl-10-oxa-3-aza-tricyclo[5.2.1.0^1,5]dec-8-en-4-one 
• 77704-41-7 (1S,5S,7R)-3-((R)-2-Hydroxy-1-phenyl-ethyl)-6,6-dimethyl-10-oxa-3-aza-tricyclo[5.2.1.0^1,5]decan-4-one 
• 132168-59-3 (1S,2S,4R)-1-Bromomethyl-3,3-dimethyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester 
• 72445-00-2 (1S,2S,4R)-1-Hydroxymethyl-3,3-dimethyl-7-oxa-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester 
• 77704-70-2 (-)-(R)-N-<(Furan-2-yl)methyl>-N-(2-hyydroxy-1-phenylethyl)-3-methylbut-2-enamid 
• 62994-45-0 hydroxymethyl-2 trimethyl-1,3,3 oxa-7 bicyclo<2.2.1>heptane exo 

Downstream Products

• 77704-42-8 (1S,2S,4R)-2-Benzenesulfonylmethyl-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]heptane 

Relevant academic research and scientific papers

SYNTHESES D'INTERMEDIAIRES PRESENTANT LE MOTIF STRUCTURAL DU TRIMETHYL-1,3,3 OXA-7 BICYCLOHEPTANE

Starting from geraniol, both exo- or endo-2-alkyl-1,3,3-trimethyl-7-oxa bicycloheptane could be prepared through two short sequences.The key step to obtain the 7-oxanorbornane moiety involves either the elimination of a selenenyl intermediate or an

THE ASYMMETRIC DIELS-ALDER REACTIONS OF α,β-UNSATURATED CARBOXYLIC AMIDES DERIVED FROM (-)-PHENYLGLYCINOL AND THE ASYMMETRIC TOTAL SYNTHESIS OF (+)-FARNESIFEROL C

The asymmetric intramolecular Diels-Alder reactions of α,β-unsaturated carboxylic amides derived from (-)-phenylglycinol were studied and successfully applied to the asymmetric total synthesis of (+)-farnesiferol C.