77704-41-7

Upstream product

• 77704-39-3 (-)-(1R,5S,7S)-3-[(1R)-2-hydroxy-1-phenylethyl]-6,6-dimethyl-10-oxa-3-azatricyclo[5.2.1.0^1,5]dec-8-en-4-one 
• 98-01-1 furfural 
• 77704-70-2 (-)-(R)-N-<(Furan-2-yl)methyl>-N-(2-hyydroxy-1-phenylethyl)-3-methylbut-2-enamid 
• 77704-39-3 (1S,5S,7R)-3-((R)-2-Hydroxy-1-phenyl-ethyl)-6,6-dimethyl-10-oxa-3-aza-tricyclo[5.2.1.0^1,5]dec-8-en-4-one 
• 132168-56-0 (-)-(R)-<2--N-(3-methylbut-2-enoyl)amino>-2-phenylethyl>-3-methyl-but-2-enoat 
• 132168-60-6 (-)-(R)-2<<(Furan-2-yl)methyl>amino>-2-phenylethanol 
• 56613-80-0 D-2-phenylglycinol 

Downstream Products

• 122274-03-7 Toluene-4-sulfonic acid (1S,2R,4R)-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl ester 
• 77704-42-8 (1S,2S,4R)-2-Benzenesulfonylmethyl-1,3,3-trimethyl-7-oxa-bicyclo[2.2.1]heptane 

Relevant academic research and scientific papers

Carotenoids with 7-Oxabicycloheptyl End Groups. Synthesis of (2S,5R,6S,2'S,5'R,6'S)-2,5:2',5'-Diepoxy-5,6,5',6'-tetrahydro-β,β-carotene

Mukayama's ester 6 (methyl (1S,2R,5S)-2,5-epoxy-2,6,6-trimethylcyclohexane-1-carboxylate) was transformed in a few conventional steps into the title compound 14.Its CD curve was found to be significantly different from that of the analogous 3,6-epoxide, a

THE ASYMMETRIC DIELS-ALDER REACTIONS OF α,β-UNSATURATED CARBOXYLIC AMIDES DERIVED FROM (-)-PHENYLGLYCINOL AND THE ASYMMETRIC TOTAL SYNTHESIS OF (+)-FARNESIFEROL C

The asymmetric intramolecular Diels-Alder reactions of α,β-unsaturated carboxylic amides derived from (-)-phenylglycinol were studied and successfully applied to the asymmetric total synthesis of (+)-farnesiferol C.