122278-07-3Relevant academic research and scientific papers
ENYNONES IN ORGANIC SYNTHESIS. I. SPIROANNULATION BY TANDEM OXY-COPE REARRANGEMENT-ELECTROCYCLIC RING CLOSURE
Jacobi, Peter A.,Armacost, Lisa M.,Kravitz, Joseph I.,Martinelli, Michael J.,Selnick, Harold G.
, p. 6865 - 6868 (1988)
Bis-acetylenic alcohols of proper design undergo a facile oxy-Cope rearrangement to afford mixtures of E- and Z-enynones.These latter compounds afford methylenecyclopentenones upon enolization and electrocyclic ring closure.
