Tetrahedron Letters p. 6865 - 6868 (1988)
Update date:2022-09-26
Topics:
Jacobi, Peter A.
Armacost, Lisa M.
Kravitz, Joseph I.
Martinelli, Michael J.
Selnick, Harold G.
Bis-acetylenic alcohols of proper design undergo a facile oxy-Cope rearrangement to afford mixtures of E- and Z-enynones.These latter compounds afford methylenecyclopentenones upon enolization and electrocyclic ring closure.
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