122279-46-3Relevant academic research and scientific papers
3H-Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β-Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms
Kl?cker, Hans,Tendyck, Jonas C.,Keweloh, Lukas,Hepp, Alexander,Uhl, Werner
, p. 4793 - 4807 (2019/03/13)
A facile method for the efficient synthesis of 3H-phosphaallenes, R?P=C=C(H)?R′, is presented, which comprises treatment of dialkynylphosphines with dialkylaluminium hydrides (hydroalumination) and elimination of aluminium alkynides from intermediate alke
3H-PHOSPHAALLEN-ALKINYL-1H-PHOSPHAN-TAUTOMERE
Maerkl, G.,Reitinger, S.
, p. 463 - 466 (2007/10/02)
The title compounds are prepared for the first time by reaction of 2,4,6-tris(tert-butyl)phenylchlorophosphane with Li-resp.Mg-acetylides
