122317-08-2

Upstream product

• 452064-38-9 [Re(Br)(CO)3(4,4'-dimethyl-2,2'-bipyridine)] 
• 639-58-7 triphenyltin chloride 
• 122279-31-6 fac-[Re(Br)(CO)3(4,4'-di-methyl-2,2'-bipyridine)] 

Downstream Products

• 99666-78-1 rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl 
• 639-58-7 triphenyltin chloride 
• 113110-81-9 (t-Bu)N(O)Re(CO)3(4,4'-dimethyl-2,2'-bipyridine) 
• 1064-10-4 hexaphenylditin 

Relevant academic research and scientific papers

fac-tricarbonyl(4,4′-dimethyl-2,2′-bipyridine)triphenyltin(II) rhenium(I)

The title organometallic compound, fac-tricarbonyl-2k3C-(4, 4′-dimethyl-2,2′-bipyridine)-2k2N,N′-triphenyl- 1k3C1-tin(II)-rhenium(I)(Sn - Re), [ReSn(C 6H5)3(C12H12N 2)(CO)3], contains three unique π-π stacking interactions. The result is an infinite chain of uninterrupted alternating intra- and intermolecular offset π-π stacking interactions throughout the crystal lattice. This extended π-π stacking arrangement, and an additional isolated intramolecular π-π interaction between the remaining 4,4′-dimethyl-2,2′-bipyridine ring and a second phenyl group, impose geometric constraints on the Re and Sn atoms, yielding distorted octahedral and tetrahedral coordinations, respectively, for the metal centers.