Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)

Base Information

Chemical Name:Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)
CAS No.:122317-08-2
Molecular Formula:C₃₃H₂₇N₂O₃ReSn
Molecular Weight:804.506
Hs Code.:

Ph<sub>3</sub>SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)

Synonyms:Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)

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Chemical Property of Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)

Chemical Property:

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Technology Process of Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)

There total 2 articles about Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 452064-38-9,122279-31-6
[Re(Br)(CO)3(4,4'-dimethyl-2,2'-bipyridine)]

: 639-58-7
triphenyltin chloride

: 122317-08-2
fac-tricarbonyl-2κ3C-(4,4'-dimethyl-2,2'-bipyridine)-2κ2N,N'-triphenyl-1κ3C1-tin(II)-rhenium(I)(Sn-Re)

Guidance literature:: With Na/K_2.8; In tetrahydrofuran; N2-atmosphere; reduction of Re-compd. with Na/K-alloy, addn. of Sn-compd.;
DOI:10.1016/S0020-1693(00)90570-X

Reference yield:

: 122279-31-6,452064-38-9
fac-[Re(Br)(CO)3(4,4'-di-methyl-2,2'-bipyridine)]

: 639-58-7
triphenyltin chloride

: 122317-08-2
fac-tricarbonyl-2κ3C-(4,4'-dimethyl-2,2'-bipyridine)-2κ2N,N'-triphenyl-1κ3C1-tin(II)-rhenium(I)(Sn-Re)

Guidance literature:: With Na-Hg; In tetrahydrofuran; mixt. of fac-Re complex and Na-Hg in THF stirred for 2 h, mixt. allowed to settle, supernatant drawn off and added dropwise to Ph3SnCl in THF infoil-covered flask, mixt. stirred for 2 h; according to Luong et al., J . Am. Chem. Soc. 102 (1980) 7892-7900; evapd., residue triturated with toluene, combined extracts evapd., residue dissolved in THF, pptn. by addn. of hexane;
DOI:10.1107/S0108270104013836

Reference yield:

: 56-23-5
tetrachloromethane

: 122317-08-2
Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)

: 75-09-2
dichloromethane

: 99666-78-1,103667-38-5
rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl

: 639-58-7
triphenyltin chloride

Guidance literature:: In dichloromethane; Irradiation (UV/VIS); N2-atmosphere; 0.5 M CCl4 in CH2Cl2, irradiation into MLCT UV-band of title compd.; not isolated, reaction followed by UV/VIS spectroscopy and quantum yielddetn.;
DOI:10.1016/s0020-1693(96)05203-6