122345-83-9Relevant academic research and scientific papers
A New Preparative Route to Phosphaethynes from Dichlorophosphaethenes by Lithiation, Photoisomerization, and Re-lithiation Involving Migration
Yoshifuji, Masaaki,Kawanami, Hajime,Kawai, Yoshinori,Toyota, Kozo,Yasunami, Masafumi,et al.
, p. 1053 - 1056 (2007/10/02)
2-(2,4,6-Tri-t-butylphenyl)-1-phosphaethyne was prepared from 2,2-dichloro-1-(2,4,6-tri-t-butylphenyl)-1-phosphaethene by lithiation of anti-chloro atom followed by hydrolysis, photoisomerization, and repeated lithiation involving migration.The present me
SYNTHESE UND REAKTIONEN DER 2,4,6-TRI-TERT-BUTYLPHENYLDIHALOGENMETHYLENPHOSPHANE1
Appel, Rolf,Casser, Carl,Immenkeppel, Michael
, p. 3551 - 3554 (2007/10/02)
The synthesis of dihalogenated phosphaalkanes 2a,b is reported.After metallation with n-BuLi they could be substituted by halogenated compounds.
