122345-84-0

Upstream product

• 126370-37-4 (1R,2R)-3-Chloro-3-methyl-1,2-bis-(2,4,6-tri-tert-butyl-phenyl)-diphosphirane 
• 100281-24-1 2,2-dichloro-1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethene 
• 100281-25-2 C₁₉H₃₀Cl₃P 
• 122345-83-9 C₁₉H₂₉ClLiP 
• 74-88-4 methyl iodide 
• 92957-42-1 E-2-chloro-1-(2,4,6-tri-t-butylphenyl)-1-phospha-ethylene 

Relevant academic research and scientific papers

Photochemistry of Functionalized Diphosphiranes

The structure of the functionalized trans-diphosphiranes 1a-e, obtained by reaction of halogenocarbenes with the trans-diphosphene is confirmed by X-ray diffraction.The photolysis of 1a-e lead to the functionalized cis- and trans-1,3-diphosphapropenes 2a-e as major products, via the diphosphiranyl 7 and the diphosphapropenyl 8 radical intermediates.The latter are characterized by ESR spectroscopy using the spin-trap method.The trans configuration of 2a is also confirmed by X-ray diffraction.The mechanism of the ring-opening, involving P-P bond rupture, is discussed.

Formation of a Phospha-alkyne via Migration of the Phenyl Group from Phosphorus to Carbon

E-2-Chloro-1-(2,4,6-tri-t-butylphenyl)-1-phospha-ethylene was allowed to react with t-butyllithium as a base to give 2-(2,4,6-tri-t-butylphenyl)-1-phospha-acetylene, suggesting the generation of a phosphorus analogue of isonitrile followed by migration of

SYNTHESE UND REAKTIONEN DER 2,4,6-TRI-TERT-BUTYLPHENYLDIHALOGENMETHYLENPHOSPHANE1

The synthesis of dihalogenated phosphaalkanes 2a,b is reported.After metallation with n-BuLi they could be substituted by halogenated compounds.