1223592-79-7Relevant academic research and scientific papers
Super silyl stereo-directing groups for complete 1,5-Syn and -anti stereoselectivities in the aldol reactions of β-siloxy methyl ketones with aldehydes
Yamaoka, Yousuke,Yamamoto, Hisashi
, p. 5354 - 5356 (2010)
In this communication, we report that substrate-controlled 1,5-syn and -anti stereoinduction in the aldol reaction of β-tris(trialkylsilyl)siloxy methyl ketones can be achieved with high diastereoselectivities. Tris(trialkylsilyl)silyl groups are easily p
