122364-55-0Relevant academic research and scientific papers
CHLOROSILANE-ACCELERATED CONJUGATE ADDITION OF CATALYTIC AND STOICHIOMETRIC ORGANOCOPPER REAGENTS
Matsuzawa, Satoshi,Horiguchi, Yoshiaki,Nakamura, Eiichi,Kuwajima, Isao
, p. 349 - 362 (2007/10/02)
Trialkylsilyl chlorides, particularly in combination with hexamethylphosphoramide or 4-dimethylaminopyridine, dramatically accelerates the conjugate addition of catalytic and stoichiometric organocopper reagents onto enones, enals, and enoates, in which very high degrees of stereo- and chemoselectivities were observed.
