122406-32-0

Upstream product

• 538-51-2 benzylidene phenylamine 
• 116386-54-0 (-)-1-chloroundecyl p-tolyl sulfoxide 
• 119487-93-3 1-chlorodecanyl p-tolyl sulfoxide 

Downstream Products

• 119487-96-6 (2R,3R)-2-Decyl-1,3-diphenyl-2-(toluene-4-sulfinyl)-aziridine 
• 122406-35-3 (-)-(2R,3S)-1,2-diphenyl-3-decylaziridine 
• 122333-59-9 (S)-(+)-1-phenyl-1-(phenylamino)dodecane 
• 1519-40-0 ethyl p-tolyl sulfoxide 
• 119487-96-6 (2R,3R)-2-Decyl-1,3-diphenyl-2-((S)-toluene-4-sulfinyl)-aziridine 
• 122333-58-8 Phenyl-[(R)-1-phenyl-2-((R)-toluene-4-sulfinyl)-dodecyl]-amine 
• 119487-97-7 (Z)-1,2-diphenyl-3-decylaziridine 
• 119487-96-6 (2R,3R)-2-Decyl-1,3-diphenyl-2-((S)-toluene-4-sulfinyl)-aziridine 

Relevant academic research and scientific papers

Stereospecific Desulfinylation of Sulfinylaziridines with Alkylmetals: A Novel Synthesis Including Asymmetric Synthesis of (Z)-N-Arylaziridines and Some Mechanistic Studies

Addition of the anion derived from 1-chloroalkyl p-tolyl sulfoxides 3 to N-arylimines 4 afforded chloro amines 5 in high yields with complete 1,2- and 1,3-asymmetric induction.Treatment of these chloro amines 5 with potassium tert-butoxide gave sulfinylaz

STEREOSPECIFIC DESULFINYLATION OF SULFINYLAZIRIDINES WITH ETHYLMAGNESIUM BROMIDE: A NOVEL SYNTHESIS OF (Z)-N-ARYLAZIRIDINES

A novel synthesis of (Z)-N-arylaziridines was realised by the stereospecific desulfinylation of (E)-(N-aryl)sulfinylaziridines which were synthesized from 1-chloroalkyl p-tolyl sulfoxides and N-arylimines in high yields.