119487-96-6

Upstream product

• 119487-95-5 [(1R,2R)-2-Chloro-1-phenyl-2-(toluene-4-sulfinyl)-dodecyl]-phenyl-amine 
• 119487-95-5 [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-dodecyl]-phenyl-amine 
• 122406-32-0 [(1R,2R)-2-Chloro-1-phenyl-2-((R)-toluene-4-sulfinyl)-dodecyl]-phenyl-amine 
• 538-51-2 benzylidene phenylamine 
• 223392-45-8 1-((R)-1-Chloro-undecane-1-sulfinyl)-4-methyl-benzene 
• 2050-77-3 Iododecane 
• 116386-54-0 (-)-1-chloroundecyl p-tolyl sulfoxide 
• 31350-91-1 (R)-chloromethyl p-tolyl sulfoxide 
• 119487-93-3 1-chlorodecanyl p-tolyl sulfoxide 

Downstream Products

• 119487-97-7 (Z)-1,2-diphenyl-3-decylaziridine 
• 1519-40-0 ethyl p-tolyl sulfoxide 
• 122406-35-3 (-)-(2R,3S)-1,2-diphenyl-3-decylaziridine 
• 302354-75-2 (2R,3R)-2-Decyl-2-(3-methoxy-benzyl)-1,3-diphenyl-aziridine 

Relevant academic research and scientific papers

Alkylation of nonstabilized aziridinylmagnesiums catalyzed by Cu(I) iodide: A new synthesis of amines, including optically active form, bearing a quaternary chiral center

A high-yield alkylation of aziridinylmagnesiums, which were generated from sulfinylaziridines with EtMgBr by sulfoxide-magnesium exchange, with primary alkyl halides in the presence of Cu(I) iodide as a catalyst, was realized. The alkylated aziridines were converted in quantitative yield to amines bearing a quaternary chiral center by hydrogenation with Pd(OH)2. A synthesis of the optically active amines, bearing a quaternary chiral center, was realized, starting from optically active (R)-chloromethyl p-tolyl sulfoxide, in good overall yield by the presented method. (C) 2000 Elsevier Science Ltd.

Stereospecific Desulfinylation of Sulfinylaziridines with Alkylmetals: A Novel Synthesis Including Asymmetric Synthesis of (Z)-N-Arylaziridines and Some Mechanistic Studies

Addition of the anion derived from 1-chloroalkyl p-tolyl sulfoxides 3 to N-arylimines 4 afforded chloro amines 5 in high yields with complete 1,2- and 1,3-asymmetric induction.Treatment of these chloro amines 5 with potassium tert-butoxide gave sulfinylaz

STEREOSPECIFIC DESULFINYLATION OF SULFINYLAZIRIDINES WITH ETHYLMAGNESIUM BROMIDE: A NOVEL SYNTHESIS OF (Z)-N-ARYLAZIRIDINES

A novel synthesis of (Z)-N-arylaziridines was realised by the stereospecific desulfinylation of (E)-(N-aryl)sulfinylaziridines which were synthesized from 1-chloroalkyl p-tolyl sulfoxides and N-arylimines in high yields.