122444-48-8Relevant academic research and scientific papers
Hydrometallation (M = Al, Ga) of Silicon- And Germanium-centred Oligoalkynes
Uhl, Werner,Bohnemann, J?rg,Kappelt, Benedikt,Malessa, Kira,Rohling, Martina,Tannert, Jens,Layh, Marcus,Hepp, Alexander
, p. 1333 - 1347 (2014)
Treatment of a variety of alkyl- And arylsilanes, R4-nSi(C≡C-R′)n, and -germanes, R4-nGe(C≡CR 0)n (1-7), with equimolar quantities of the dialkylmetal hydrides HMR″2 (M = Al, Ga; R″ = CMe3, CH2CHMe2)
Sodium triethylborohydride as a catalyst for the dehydrogenative silylation of terminal alkynes with hydrosilanes
Skrodzki, Maciej,Witomska, Samanta,Pawlu?, Piotr
supporting information, p. 5948 - 5951 (2018/05/14)
The first example of sodium triethylborohydride-catalyzed C(sp)-H bond silylation is reported. The reaction of aromatic and aliphatic alkynes with aromatic hydrosilanes and hydrosiloxanes proceeded in a highly selective manner to afford dehydrocoupling pr
