1224587-98-7Relevant academic research and scientific papers
Aspects of stereocontrol in the L-Selectride reduction of 4-acyl-1,3-dioxolane derivatives
Robertson, Jeremy,Unsworth, William P.,Lamont, Scott G.
experimental part, p. 2363 - 2372 (2010/06/16)
The application of L-Selectride, either alone or in combination with ZnCl2, to aryl ketones 1, 8 and 11 resulted in highly anti-stereoselective reduction. In contrast, lactols 22 and 23 gave a moderate syn-preference using L-Selectride alone an
C-Glycosides. 7. Stereospecific C-Glycosylation of Aromatic and Heterocyclic Rings
Czernecki, S.,Ville, G.
, p. 610 - 612 (2007/10/02)
Stereospecific C-glycosylation of aromatic and heterocyclic rings can be realized by reacting the corresponding organolithium derivatives with benzylated lactones and reducing the so-obtained lactols with triethylsilane in the presence of boron trifluorid
NEW APPROACHES TO SYNTHETIC RECEPTORS. STUDIES ON THE SYNTHESIS AND PROPERTIES OF MACROCYCLIC C-GLYCOSYL COMPOUNDS AS CHIRAL, WATER-SOLUBLE CYCLOPHANES
Wilcox, Craig S.,Cowart, Marlon D.
, p. 141 - 160 (2007/10/02)
In an approach for the preparation of macrocyclic C-glycosyl compounds, the C-glycosyl residue is synthesized by acid assisted reduction of a cyclic hemiacetal with sodium cyanoborohydride.Macrocyclic formation is effected by the reaction of a symmetrical
