1224692-33-4Relevant academic research and scientific papers
Cleavage of the C-S bond with the formation of a binuclear copper complex with 2-thiolato-3-phenyl-5-(pyridine-2-ylmethylene)-3,5-dihydro-4H-imidazole-4- one. A new mimic of the active site of N2O reductase
Majouga, Alexander G.,Beloglazkina, Elena K.,Moiseeva, Anna A.,Shilova, Olga V.,Manzheliy, Eugeniy A.,Lebedeva, Maria A.,Davies, E. Stephen,Khlobystov, Andrei N.,Zyk, Nikolay V.
, p. 6290 - 6293 (2013)
The treatment of the ligands with copper(ii) chloride dihydrate led to the formation of a binuclear copper complex with a [Cu+1.5Cu +1.5] redox state as a result of C-S bond cleavage in the course of the reaction. This complex catalyses the electrochemical reduction of nitrous oxide and triphenyl phosphine oxidation under N2O action.
Formation of CuI(CH3CN)4ClO4 in the reactions of copper(II) perchlorate with acetonitrile in the presence of sulfur-containing organic compounds
Beloglazkina,Shimorsky,Mazhuga,Shilova,Tafeenko,Zyk
experimental part, p. 1504 - 1508 (2009/12/04)
Cu(ClO4)2?6H2O was shown to react with 2,2?-[propane-1,3-diylbis(thio-2-phenylnemethylidene]-bis(3-pyridylamine) (I) or (5Z)-2-ethoxycarbonylmethyl-(2-pyridylmethylidene)-3,5-dihydro-4H- imidazol-4-one (II) in the presence of CH3CN with the reduction of copper(II) to copper(I) and the formation of the tetrahedral complex Cu I(CH3CN)4ClO4 (III). In the course of the reaction the organic ligands I and II were oxidized to the corresponding sulfoxides.
