1224869-16-2

Basic information

• Product Name: (S)-4-(4-bromophenyl)-4-(diphenylphosphinyl)butan-2-one
• Synonyms: (S)-4-(4-bromophenyl)-4-(diphenylphosphinyl)butan-2-one
• CAS NO: 1224869-16-2
• Molecular Weight: 427.277
• Mol File: 1224869-16-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-4-(4-bromophenyl)-4-(diphenylphosphinyl)butan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-(4-bromophenyl)-4-(diphenylphosphinyl)butan-2-one(1224869-16-2)
• EPA Substance Registry System: (S)-4-(4-bromophenyl)-4-(diphenylphosphinyl)butan-2-one(1224869-16-2)

Safety Data

• Hazardous Substances Data: 1224869-16-2(Hazardous Substances Data)

Upstream product

• 1244965-21-6 C₂₂H₂₀BrOP 
• 3815-31-4 4-(4-bromophenyl)but-3-en-2-one 
• 829-85-6 diphenylphosphane 

Relevant articles and documents

NHC-copper-catalyzed asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated ketones

N-Heterocyclic carbene-copper-catalyzed asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated ketones was developed for the synthesis of chiral phosphorus derivatives in high yields with moderate enantioselectivity under mild conditions.

Unsymmetrical chiral PCN pincer palladium(II) and nickel(II) complexes with aryl-based aminophosphine-imidazoline ligands: Synthesis via aryl C-H activation and asymmetric addition of diarylphosphines to enones

Figure Persented: Chiral 3-(2′-imidazolinyl)anilines 3a-c were easily synthesized by converting the carboxyl and nitro groups in commercially available 3-nitrobenzoic acid to chiral imidazoline and amine, respectively. The one-pot phosphorylation/metalati