122491-01-4Relevant academic research and scientific papers
Palladium-Catalyzed Trimethylenemethane Reaction To Form Methylenetetrahydrofurans. Aldehyde and Ketone Substrates and the Tin Effect
Trost, Barry M.,King, Steven A.,Schmidt, Thomas
, p. 5902 - 5915 (2007/10/02)
The palladium-catalyzed trimethylenemethane (TMM) cycloaddition of carbonyl compounds has been shown to have a strong dependence upon the presence of cocatalysts such as tri-n-butyltin acetate, di-n-butyltin diacetate, or trimethyltin acetate.High-yieldin
Heterocyclic Acceptors in Diastereoselective Palladium Mediated Cycloadditions
Trost, Barry M.,King, Steven A.,Nanninga, Thomas N.
, p. 15 - 18 (2007/10/02)
Whereas cyclohexenones and ketones are poor acceptors for palladium mediated cycloadditions of 2-trimethylsilylmethylallyl acetate, oxygen heterocycles bearing such functionality react smoothly and with high diastereoselectivity.
