122504-93-2

Basic information

• Product Name: (2,5-Dimethoxy-benzylsulfanyl)-acetic acid methyl ester
• Synonyms: (2,5-Dimethoxy-benzylsulfanyl)-acetic acid methyl ester
• CAS NO: 122504-93-2
• Molecular Weight: 256.323
• Mol File: 122504-93-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,5-Dimethoxy-benzylsulfanyl)-acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2,5-Dimethoxy-benzylsulfanyl)-acetic acid methyl ester(122504-93-2)
• EPA Substance Registry System: (2,5-Dimethoxy-benzylsulfanyl)-acetic acid methyl ester(122504-93-2)

Safety Data

• Hazardous Substances Data: 122504-93-2(Hazardous Substances Data)

Upstream product

• 60732-17-4 2,5-dimethoxybenzyl bromide 
• 33524-31-1 2,5-dimethoxybenzyl alcohol 
• 2365-48-2 Methyl thioglycolate 

Downstream Products

• 122504-99-8 (2,5-Dimethoxy-phenylmethanesulfonyl)-acetic acid methyl ester 

Relevant articles and documents

Intramolecular rhodium carbenoid insertions into aromatic C-H bonds. Preparation of 1,3-dihydrothiophene 2,2-dioxides fused onto aromatic rings

The preparation of 1-carboalkoxy-1,3-dihydrobenzenothiophene 2,2-dioxides via rhodium acetate or rhodium trifluoro-acetate catalyzed decomposition of α-diazo-β-arylmethanesulfonyl esters is described.The reaction has been extended to yield 1,3-dihydrothiophene 2,2-dioxides fused to the 2,3 position of thiophene and indole, but not of furans.In the latter case products derived from the opening of the furan ring were obtained.Key words: synthesis, 1-carboalkoxy-1,3-dihydrobenzothiophene 2,2-dioxides, intramolecular carbenoid insertions, rhodium acetate catalysis.