122601-62-1

Basic information

• Product Name: (1S,2S,6R,7R,10R)-4-Oxa-tricyclo[5.2.1.0^2,6]dec-8-en-10-ol
• CAS NO: 122601-62-1
• Molecular Weight: 152.193
• Mol File: 122601-62-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,2S,6R,7R,10R)-4-Oxa-tricyclo[5.2.1.0^2,6]dec-8-en-10-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,6R,7R,10R)-4-Oxa-tricyclo[5.2.1.0^2,6]dec-8-en-10-ol(122601-62-1)
• EPA Substance Registry System: (1S,2S,6R,7R,10R)-4-Oxa-tricyclo[5.2.1.0^2,6]dec-8-en-10-ol(122601-62-1)

Safety Data

• Hazardous Substances Data: 122601-62-1(Hazardous Substances Data)

Upstream product

• 122601-50-7 endo-10,10-dimethoxy-4-oxatricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione 
• 15208-02-3 endo-1,4,5,6-tetrachloro-7,7-dimethoxy-2,3-bis-hydroxymethylbicyclo[2.2.1]hept-5-ene 
• 122601-54-1 endo-7,7-dimethoxy-2,3-bis-hydroxymethylbicyclo[2.2.1]hept-5-ene 
• 122601-57-4 4-oxatricyclo[5.2.1.0^2,6]dec-8-en-10-one 
• 20379-81-1 endo-1,7,8,9-tetrachloro-10,10-dimethoxy-4-oxatricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione 
• 2207-27-4 5,5-dimethoxy-1,2,3,4-tetrachlorocyclopentadiene 

Relevant articles and documents

π-Facial selectivities in nucleophilic additions to 4-hetero-tricyclo[5.2.1.02,6]decan-10-ones and 4-hetero-tricyclo[5.2.1.02,6]dec-8-en-10-ones: An experimental and computational study

Several endo-tricyclo[5.2.1.02,6]decan-10-ones and endo-tricyclo[5.2.1.02,6]dec-8-en-10-ones with hetero atom modifications at the distal C-4 position have been subjected to hydride reduction. π-Face selectivities in these systems are largely governed by the same electronic factors that were earlier identified in the case of the norbornyl system. A computational study demonstrates good predictability at the semi-empirical level.

Absence of heteroatom kinetic effects in π-routes to carbocations

In solvolyses of prototypical tricyclic and bicyclic heterocycles, suitably positioned oxygen, nitrogen, or sulfur ring-atoms have little net kinetic influence on π routes to carbocations.