122616-22-2

Upstream product

• 71242-58-5 (1S,2R,4R)-(-)-10-mercaptoisoboneol 
• 122616-24-4 (Z)-3-Benzenesulfonyl-3-triethylsilanyl-propenal 
• 122616-23-3 (Z)-3-Benzenesulfonyl-3-triethylsilanyl-prop-2-en-1-ol 
• 122647-13-6 (3-(methoxymethoxy)prop-1-yn-1-yl)(phenyl)sulfane 
• 617-86-7 triethylsilane 

Downstream Products

• 122616-27-7 (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane 
• 102838-84-6 (R)-1-(phenylsulphonyl)propan-2-ol 
• 122616-28-8 (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1,5-dimethyl-hex-4-enyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane 

Relevant academic research and scientific papers

ASYMMETRIC SYNTHESIS VIA HETEROCONJUGATE ADDITION USING ELIEL'S CAMPHOR TEMPLATE

A new asymmetric synthesis is reported that includes carbon-carbon bond formation based upon heteroconjugate addition with Eliel's 1R-(+)-camphor derivative as a template.This method showed high enantiomeric excess under chelation control affected by the solvent polarity and by the salt present in the reaction media. (+)-citronellal was synthesized as a proof of this method.