122616-28-8

Basic information

• Product Name: (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1,5-dimethyl-hex-4-enyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane
• Synonyms: (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1,5-dimethyl-hex-4-enyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane
• CAS NO: 122616-28-8
• Molecular Weight: 448.691
• Mol File: 122616-28-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1,5-dimethyl-hex-4-enyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1,5-dimethyl-hex-4-enyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane(122616-28-8)
• EPA Substance Registry System: (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1,5-dimethyl-hex-4-enyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane(122616-28-8)

Safety Data

• Hazardous Substances Data: 122616-28-8(Hazardous Substances Data)

Upstream product

• 122616-22-2 [(Z)-1-Benzenesulfonyl-2-((1S,4R,6R,8R)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undec-4-yl)-vinyl]-triethyl-silane 
• 122616-21-1 [(Z)-1-Benzenesulfonyl-2-((1S,4R,6R,8R)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undec-4-yl)-vinyl]-trimethyl-silane 
• 122616-23-3 (Z)-3-Benzenesulfonyl-3-triethylsilanyl-prop-2-en-1-ol 
• 122616-24-4 (Z)-3-Benzenesulfonyl-3-triethylsilanyl-propenal 
• 122616-25-5 (Z)-3-Benzenesulfonyl-3-trimethylsilanyl-prop-2-en-1-ol 
• 122616-26-6 (Z)-3-Benzenesulfonyl-3-trimethylsilanyl-propenal 
• 122647-13-6 (3-(methoxymethoxy)prop-1-yn-1-yl)(phenyl)sulfane 
• 122616-27-7 (1S,4R,6R,8R)-4-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-11,11-dimethyl-5-oxa-3-thia-tricyclo[6.2.1.0^1,6]undecane 
• 870-63-3 prenyl bromide 

Downstream Products

• 2385-77-5 (R)-Citronellal 
• 106-72-9 (R)-(-)-2,6-dimethyl-5-heptenal 

Relevant articles and documents

ASYMMETRIC SYNTHESIS VIA HETEROCONJUGATE ADDITION USING ELIEL'S CAMPHOR TEMPLATE

A new asymmetric synthesis is reported that includes carbon-carbon bond formation based upon heteroconjugate addition with Eliel's 1R-(+)-camphor derivative as a template.This method showed high enantiomeric excess under chelation control affected by the solvent polarity and by the salt present in the reaction media. (+)-citronellal was synthesized as a proof of this method.