122637-39-2Relevant articles and documents
Copper(ii)-hydroxide facilitated C-C bond formation: The carboxamido pyridine system: Versus the methylimino pyridine system
Fan, Weibin,Huang, Deguang,Li, Yinghua,Xiang, Shiqun,Xie, Xingkun,Zhang, Zilong
, p. 12189 - 12196 (2020/10/02)
A copper(ii)-hydroxide-induced carbon-carbon bond formation reaction is explored with the synthesis of an asymmetric carboxamido-methylimino pyridine Cu(i) complex of [CuI(py(N-CO)(NC-C)ph2Me2)2]- (12). Two imine-methyl groups are coupled to form a bridge
Linkage isomerism in transition-metal complexes of mixed (arylcarboxamido)(arylimino)pyridine ligands
Boyce, David W.,Salmon, Debra J.,Tolman, William B.
, p. 5788 - 5796 (2014/06/23)
The synthesis of a series of asymmetric mixed 2,6-disubstituted (arylcarboxamido)(arylimino)pyridine ligands and their coordination chemistry toward a series of divalent first-row transition metals (Cu, Co, and Zn) have been explored. Complexes featuring both anionic N,N,N″-carboxamido and neutral O,N,N-carboxamide coordination have been prepared and characterized by X-ray crystallography, cyclic voltammetry, and UV-visible and EPR spectroscopy. Specifically, RLM(X) (M = Cu; X = Cl-, OAc-) and RL(H)MX2 (M = Cu, Co, Zn; X = Cl-, SbF 6-) complexes that feature N,N,N″- or O,N,N-coordination are presented. Base-induced linkage isomerization from O,N,N-carboxamide to N,N,N″-carboxamido coordination is also confirmed by multiple forms of spectroscopy.
Polynuclear lanthanide complexes of a series of bridging ligands containing two tridentate N,N′,O-donor units: Structures and luminescence properties
Ronson, Tanya K.,Adams, Harry,Harding, Lindsay P.,Pope, Simon J. A.,Sykes, Daniel,Faulkner, Stephen,Ward, Michael D.
, p. 1006 - 1022 (2007/10/03)
A set of three potentially bridging ligands containing two tridentate chelating N,N′,O-donor (pyrazole-pyridine-amide) donors separated by an o, m, or p-phenylene spacer has been prepared and their coordination chemistry with lanthanide(iii) ions investig
