122663-64-3Relevant academic research and scientific papers
The synthesis of spirolactones using indium-mediated allylation of cyclic anhydrides and ring-closing olefin metathesis
Sabitha,Reddy,Babu,Yadav
, p. 1787 - 1789 (2001)
A variety of spirolactones are prepared from cyclic anhydrides via indium-mediated allylation and ring-closing olefin metathesis (RCM) reaction as key steps.
Direct construction of quaternary carbon center utilizing an allylsamarium bromide reagent
Li, Zhifang,Zhang, Yongmin
, p. 5301 - 5306 (2002)
Direct geminal diallylation of lactones, lactams and acyclic amides containing a N-H bond has been achieved in the presence of allylsamarium bromide. By applying this method, quaternary carbons have been constructed, and 2,2-diallylated cyclic ethers, 2,2-diallylated nitrogen heterocycles and diallylated amides were synthesized in moderate to good yields under mild conditions.
Mild double allylboration reactions of nitriles and acid anhydrides using potassium allyltrifluoroborate
Ramadhar, Timothy R.,Bansagi, Jazmin,Batey, Robert A.
, p. 1216 - 1221 (2013/04/10)
The double allylboration of nitriles and acid anhydrides to form bis-allyl amines and esters, respectively, can be achieved through the use of potassium allyltrifluoroborate in the presence of boron trifluoride etherate at room temperature. The method described is relatively mild, exhibits chemoselectivity to other electrophiles present, avoids the use of metals, and features the use of an operationally stable and robust potassium organotrifluoroborate reagent.
INDIUM-INDUCED ALLYLATION OF ACID ANHYDRIDES. A FACILE SYNTHESIS OF ALLYLATED BUTENOLIDES AND PHTHALIDES
Araki, Shuki,Katsumura, Nobuhito,Ito, Hirokazu,Butsugan, Yashuo
, p. 1581 - 1582 (2007/10/02)
Indium-mediated allylation of acid anhydrides gave gem-diallyl esters, whereas with γ-substituted allylic halides monoallylated hydroxy esters were formed exclusively.
