122695-49-2Relevant articles and documents
DIASTEREOSELECTIVE ALKYLATION OF CHIRAL TIN(II) ENOLATES ONTO CYCLIC ACYL IMINIUM IONS. ASYMMETRIC TOTAL SYNTHESIS OF (-)-SUPINIDINE
Nagao, Yoshimitsu,Dai, Wei-Min,Ochiai, Masahito,Shiro, Motoo
, p. 6361 - 6380 (2007/10/02)
The scope and mechanism of the asymmetric alkylation of chiral tin(II) enolate 10 with cyclic acyl iminium ion 5 were investigated.An application of the reaction to the asymmetric synthesis of (-)-supinidine was also achieved.