122722-67-2Relevant academic research and scientific papers
3-Trimethylsilylcycloalkylidenes. γ-Silyl vs γ-Hydrogen Migration to Carbene Centers
Creary, Xavier
, p. 11378 - 11387 (2015)
A series of γ-trimethylsilyl-substituted carbenes have been studied experimentally and by computational methods. In an acyclic system, 1,3-trimethylsilyl migration successfully competes with 1,3-hydrogen migration to the carbene center. The behavior of cy
γ-Silicon Stabilization of Carbonium Ions in Solvolysis. 4. Solvolysis of cis- and trans-3-(Trimethylsilyl)cyclohexyl and -3-tert-Butylcyclohexyl p-Bromobenzenesulfonates
Shiner, V.J.,Ensinger, Mark W.,Kriz, George S.,Halley, Karen A.
, p. 653 - 661 (2007/10/02)
The solvolyses of cis- and trans-3-(trimethylsilyl)cyclohexyl and -3-tert-butylcyclohexyl p-bromobenzenesulfonates (1-4) have been examined in several ethanol- and trifluoroethanol-water solvent mixtures.The α- and β-deuterium kinetic isotope effects have
