1227303-99-2Relevant articles and documents
Synthesis of Spirocyclic Ethers by Enantioselective Copper-Catalyzed Carboetherification of Alkenols
Karyakarte, Shuklendu D.,Um, Chanchamnan,Berhane, Ilyas A.,Chemler, Sherry R.
supporting information, p. 12921 - 12924 (2018/09/25)
Spirocyclic ethers can be found in bioactive compounds. This copper-catalyzed enantioselective alkene carboetherification provides 5,5-, 5,6- and 6,6-spirocyclic products containing fully substituted chiral carbon centers with up to 99 % enantiomeric exce
Synthesis of cyclohexene derivatives from 1,5-enynes via gold-catalysis and iodocyclization: A comparative study and applications in the synthesis of 7/5- or 8/5-fused rings and biaryls
Lee, Youngun,Lim, Choongmin,Kim, Sunghwan,Shin, Seunghoon
experimental part, p. 670 - 677 (2010/08/19)
A comparative study on the Au(I)-catalyzed and IBr-promoted tandem cyclization of 1,5-enyne was reported. This study provides a meaningful mechanistic insight to the concerted nature of this tandem reaction and also provides interesting applications in the synthesis of 7/5- or 8/5-fused bicycles and biaryls.