1227468-50-9

Upstream product

• 64-19-7 acetic acid 
• 956107-32-7 methyl (1-adamantyl 5-acetamido-7,8,9-tri-O-acetyl-5-N,4-O-carbonyl-3,5-dideoxy-2-thio-D-glycero-β-D-galacto-non-2-ylopyranosid)onate 
• 40653-32-5 methyl 2,3,4-tri-O-benzyl-β-D-galactopyranoside 
• 1227468-35-0 methyl (1-adamantanyl 4,5,7,8,9-penta-O-acetyl-3-deoxy-2-thio-D-glycero-α-D-galacto-non-2-ulopyranosid)onate 
• 1227468-34-9 methyl (1-adamantanyl 4,5,7,8,9-penta-O-acetyl-3-deoxy-2-thio-D-glycero-β-D-galacto-non-2-ulopyranosid)onate 

Relevant academic research and scientific papers

Chemical diversification of sialic acid glycosides by stereospecific, chemoselective deamination

Late bloomer: Nitrosation of peracetylated sialic acid glycosides followed by treatment with sodium trifluoroethoxide and then a suitable nucleophile enables the late-stage modification of these glycosides with stereospecific replacement of the acetamido

Stereoselective synthesis of α-Keto-deoxy-D-glycero-D- galactononulosonic acid glycosides by means of the 4,5-O-carbonate protecting group

(Figure Presented) Unrivaled: A 1-adamantyl thioglycoside derivative of the nonulosonic acid KDN, carrying a 4,5-O-carbonate protecting group, is a highly efficient and a-selective KDN donor when activated using N-iodosuccinimide (NIS) and trifluoromethanesulfonic acid (TfOH). Glycosylates conducted with this protecting group do not suffer from competing glycal formation.