1227469-89-7Relevant academic research and scientific papers
Camphyl-based α-diimine palladium complexes: Highly efficient precatalysts for direct arylation of thiazoles in open-air
Chen, Fu-Min,Lu, Dong-Dong,Hu, Li-Qun,Huang, Ju,Liu, Feng-Shou
, p. 5731 - 5736 (2017/07/22)
Based on the strategy of the development of phosphine-free palladium-catalyzed direct C-H arylation, a series of camphyl-based α-diimine palladium complexes bearing sterically bulky substituents were synthesized and characterized. The palladium complexes
A convenient phosphine-free palladium-catalyzed direct arylation of thiazole under mild aerobic conditions
He, Xiao-Xi,Li, Yan-Fang,Huang, Ju,Shen, Dong-Sheng,Liu, Feng-Shou
, p. 58 - 66 (2015/12/30)
A series of bulky amine palladium complexes {[(Ar-NH2)2PdCl2]} were synthesized and characterized. The catalytic activity of the palladium complexes was evaluated via the direct C-H arylation of thiazoles with aryl bromide
Decarboxylative biaryl synthesis in a continuous flow reactor
Lange, Paul P.,Goossen, Lukas J.,Podmore, Philip,Underwood, Toby,Sciammetta, Nunzio
supporting information; experimental part, p. 3628 - 3630 (2011/05/02)
A practical protocol was developed that allows performing decarboxylative cross-coupling reactions in continuous flow reactors. Various biaryls were thus synthesized from aromatic carboxylic acids and aryl triflates using a Cu/Pd-catalyst system.
Low-Temperature Ag/Pd-catalyzed decarboxylative cross-coupling of aryl trflates with aromatic carboxylate salts
Goossen, Lukas J.,Lange, Paul P.,Rodriguez, Nuria,Linder, Christophe
supporting information; experimental part, p. 3906 - 3909 (2010/07/03)
Chemical Equation Presented At 50°C lower than the best known copper catalysts, a catalytic silver(I)/ palladium(II) system allows the decarboxylative cross-coupling of arenecarboxylates with aryl triflates at temper-atures as low as 120°C. Remarkably, polychlorinated and many heterocyclic arenecarboxylates are converted for the first time in high yields. FG = functional group.
