1227569-07-4Relevant articles and documents
Novel thione-thiol rearrangement of dithiocarbonic acid o-(2,2,6,6-tetramethylpiperidin- 1-yl) ester in the context of controlled radical polymerization
Nesvadba, Peter,Bugnon, Lucienne,Wagner, Trixie
, p. 56 - 58 (2010)
Addition of the lithium salt of N-hydroxy-2,2,6,6-tetramethylpiperidine 10 to carbon disulfide and subsequent methylation affords the rearranged dithiocarbonic acid S-methyl-S'-(2,2,6,6-tetramethylpiperidin-1-yl)- ester 9 rather than the expected xanthate ester S-methyl-O'-(2,2,6,6- tetramethylpiperidin-1-yl)-ester 8. n-utylacrylate could be polymerized with the novel compound 9 even though the polymerization was not controlled. Schweizerische Chemische Gesellschaft.