12278-58-9

Basic information

• Product Name: CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&
• Synonyms: CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&;chloronorbornadienetriphenylphosphinerhodium(i), polymer-bound fibrecat;Chloronorbornadienetriphenylphosphinerhodium(I), polymer-bound FibreCat(R)
• CAS NO: 12278-58-9
• Molecular Formula: C₂₅H₂₃ClPRh
• Molecular Weight: 0
• Mol File: 12278-58-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&(CAS DataBase Reference)
• NIST Chemistry Reference: CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&(12278-58-9)
• EPA Substance Registry System: CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&(12278-58-9)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 12278-58-9(Hazardous Substances Data)

Upstream product

• 12257-42-0 [(norbornadiene)rhodium(I)chloride]2 
• 603-35-0 triphenylphosphine 

Downstream Products

• 124273-54-7 dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I) 
• 124273-50-3 (η4-bicyclo{2.2.1}hepta-2,5-diene){3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethyl-furan-2-yl-methyl)pyrrolato-N}(triphenylphosphine)rhodium(I) 
• 85836-85-7 {Rh(SnCl₃)2(C₇H₈)(P(C₆H₅)3)}^(1-)*P(C₆H₅)3NP(C₆H₅)3⁽¹⁺⁾={Rh(SnCl₃)2(C₇H₈)(P(C₆H₅)3)}(P(C₆H₅)3NP(C₆H₅)3) 

Relevant articles and documents

Preparation and structure of [RhCl(nbd)(dmap)] (nbd = bicyclo[2.2.1]hepta-2,5-diene; dmap = 4-(N,N-dimethylamino)pyridine)

4-(N,N-Dimethylamino)pyridine (dmap) reacts with [{RhCl(nbd)}2] to give [RhCl(nbd)(dmap)] (1), which was characterized by X-ray crystallography and NMR spectroscopy. The crystal structure and dynamic behavior of the molecule in solution are compared with those of [RhCl(nbd)(PPh3)] (2).