122800-33-3Relevant academic research and scientific papers
Selective Formation of Substituted Cyclopentane Derivatives from Hexa-1,5-dienes via Oxidative Cyclization in the Presence of Pd(OAc)2-MnO2-Benzoquinone as Catalyst
Antonsson, Thomas,Heumann, Andreas,Moberg, Christina
, p. 518 - 520 (1986)
Hexa-1,5-dienes undergo oxidative ring closure catalysed by palladium acetate using p-benzoquinone-manganese dioxide as oxidant to give acetoxy-substituted methylene-cyclopentane derivatives.
Palladium-Catalized Oxidative Cyclization of 1,5-Dienes. Influence of Diferent Substitution Patterns on the Regio- and Stereochemistry of the Reaction
Antonsson, Thomas,Moberg, Christina,Tottie, Louise,Heumann, Andreas
, p. 4914 - 4929 (2007/10/02)
Oxidative cyclization of 1,5-dienes in acetic acid in the presence of the Pd(II) regenerating catalyst system Pd(OAc)2/MnO2/p-benzoquinone has been shown to yield, depending on the structure of the 1,5-diene, acetoxyexomethylenecyclopentanes or acetoxyvin
