1228185-14-5

Basic information

• Product Name: 1,3-bis(2,6-diisopropylphenyl)-2-trimethylsilylimidazolium triflate
• Synonyms: 1,3-bis(2,6-diisopropylphenyl)-2-trimethylsilylimidazolium triflate
• CAS NO: 1228185-14-5
• Molecular Weight: 610.857
• Mol File: 1228185-14-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3-bis(2,6-diisopropylphenyl)-2-trimethylsilylimidazolium triflate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-bis(2,6-diisopropylphenyl)-2-trimethylsilylimidazolium triflate(1228185-14-5)
• EPA Substance Registry System: 1,3-bis(2,6-diisopropylphenyl)-2-trimethylsilylimidazolium triflate(1228185-14-5)

Safety Data

• Hazardous Substances Data: 1228185-14-5(Hazardous Substances Data)

Upstream product

• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 244187-81-3 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene 

Downstream Products

• 1228185-20-3 1,3-bis(2,6-diisopropylphenyl)-4-trimethylsilylimidazol-2-ylidene 
• 1080030-13-2 (P(C₃H₂N₂(C₆H₃(C₃H₇)2)2))2 

Relevant articles and documents

Observation of a chloride-bridged P-P bond in the phosphorus cation [L(Cl) P(μ-Cl) P(Cl)L]+ (L = NHC)

A bridging chloride anion between two electrophilic phosphorus centers was observed for the first time in the molecular structure of the novel P-P bonded cation [LDipp2P2Cl3]+ (2+; LDipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2- ylidene). Cation 2+ is prepared by the reduction of the monophosphorus species [LDippPCl2]+ (1 +) with sodium. DFT calculations, AIM and mechanochemical (compliance constants) analyses are used to examine the bonding situation of this unusual species. The monochloro-substituted cation [LDipp2P 2Cl]+ (3+) was likewise observed as a reduction product of 1+.