1228273-82-2Relevant academic research and scientific papers
The effect of adding Crabtree's catalyst to rhodium black in direct hydrogen isotope exchange reactions
Schou, Soren Christian
, p. 376 - 381 (2009)
A new catalytic system based on rhodium black using Crabtree's catalyst as an additive for direct hydrogen isotope exchange in aromatic compounds has been investigated. The level of deuterium incorporation can be improved from for example 16 to 93%. The new catalyst mixture tolerates a variety of solvents. Copyright
Tuning up rhodium black
Schou, Soren Christian
experimental part, p. 375 - 381 (2011/05/06)
A new catalytic system based on rhodium black using Crabtree's catalyst as an additive for direct hydrogen isotope exchange in aromatic compounds has been investigated. The level of deuterium incorporation can be improved from 16% to 93%. The new catalyst mixture tolerates a variety of solvents. Other rhodium sources can be used, but the degree of crystallinity of the rhodium (metal, black or on support) plays an important role. Rhodium sources with a low degree of crystallinity had the highest catalytic activity. Copyright
