1228274-07-4Relevant academic research and scientific papers
Enantioselective synthesis of (+)-isolysergol via ring-closing metathesis
Deck, Jason A.,Martin, Stephen F.
supporting information; experimental part, p. 2610 - 2613 (2010/08/19)
The first enantioselective synthesis of (+)-isolysergol was completed in 12 steps from commercially available materials by a novel approach that features a late stage microwave-mediated, diastereomeric ring-closing metathesis catalyzed by a chiral molybdenum catalyst to simultaneously form the D ring and set the stereocenter at C(8).
