1228351-42-5

Basic information

• Product Name: NC₅H₄CH₂NHC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2
• Synonyms: NC₅H₄CH₂NHC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2
• CAS NO: 1228351-42-5
• Molecular Weight: 349.519
• Mol File: 1228351-42-5.mol

Chemical Properties

• CAS DataBase Reference: NC₅H₄CH₂NHC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: NC₅H₄CH₂NHC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2(1228351-42-5)
• EPA Substance Registry System: NC₅H₄CH₂NHC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2(1228351-42-5)

Safety Data

• Hazardous Substances Data: 1228351-42-5(Hazardous Substances Data)

Upstream product

• 123-54-6 acetylacetone 
• 24544-04-5 2,6-diisopropylbenzenamine 
• 3731-51-9 2-(Aminomethyl)pyridine 
• 205993-26-6 4-((2,6-di(isopropyl)phenyl)amino)-pent-3-en-2-one 

Downstream Products

• 1228351-36-7 (NC₅H₄CH₂NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)La(N(Si(CH₃)3)2)2 
• 1228351-33-4 (NC₅H₄CH₂NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Y(N(Si(CH₃)3)2)2 
• 1228351-25-4 (NC₅H₄CH₂NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Y(CH₂Si(CH₃)3)2 

Relevant articles and documents

Improved Synthesis of Unsymmetrical N-Aryl-N′-alkylpyridyl ?-Diketimines Using Molecular Sieves and their Lithium Complexes

The synthesis of unsymmetrical β-diketimines with N-aryl-N′-alkyl substitution require at least two condensation steps and tedious purification procedures. An improvement in the preparation of four unsymmetrical N-aryl-N′-alkylpyridyl β-diketimine ligands

Steric and chelating ring concerns on the l-lactide polymerization by asymmetric β-diketiminato zinc complexes

A series of new asymmetrical N-aryl-N′-alkyl β-diketimines bearing a pendant pyridyl group (L1H-L4H) were synthesized in a two steps reaction from acetylacetone and the corresponding appropriate amines. The reaction of these β-diketi

Single, double and triple deprotonation of a β-diketimine bearing pendant pyridyl group and the corresponding rare-earth metal complexes

A new β-diketimine bearing the pendant pyridyl group, CH 3C(2,6-(iPr)2C6H3NH) CHC(CH3)(NCH2-C5NH4) (L1), was synthesized. The reaction of L1 with one equivalent of Sc(CH 2SiMe3)3(THF)2 at room temperature gave a singly deprotonated product (L1-H)Sc(CH2SiMe3) 2 (1). Y(CH2SiMe3)3(THF)2 under the same conditions led to the unexpected dimer [(L1-H 3)Y(THF)]2 (2), in which the ligand precursor L1 was triply deprotonated. The reaction of L1 with Y(CH2SiMe 3)3(THF)2 at -35°C provided a mixture of singly deprotonated product (L1-H)Y(CH2SiMe3)2 (3) and doubly deprotonated product (L1-H2)Y(CH2SiMe 3)(THF)2 (4). The reactions of L1 with Ln[N(SiMe 3)2]3 gave only singly deprotonated products (L1-H)Ln[N(SiMe3)2]2 (5: Ln = Y; 6: Ln = La). The complexes 1, 2 and 4-6 have been characterized by single-crystal X-ray diffraction.