1228363-08-3Relevant articles and documents
Calix[4]squaramide cyclohexanediamine derivative and method for catalyzing asymmetric Michael addition and acetalization tandem reaction by using derivative
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Paragraph 0056-0061, (2019/10/10)
The invention belongs to the technical field of catalytic organic synthesis, and specifically relates to a calix[4]squaramide cyclohexanediamine derivative and a method for catalyzing an asymmetric Michael addition and acetalization tandem reaction by usi
Enantioselective asymmetric michael addition of cyclic diketones to β,γ-unsaturated α-keto esters
Wang, Yi-Feng,Wang, Ke,Zhang, Wei,Zhang, Bin-Bin,Zhang, Chi-Xiao,Xu, Dan-Qian
experimental part, p. 3691 - 3696 (2012/07/27)
An efficient, organocatalytic enantioselective addition of cyclic diketones with β,γ-unsaturated α-keto esters has been developed that affords products in high yields (up to 95%) and excellent enantioselectivity (up to >99ee) under mild conditions with a
Enantioselective synthesis of coumarins catalyzed by a bifunctional amine-thiourea catalyst
Gao, Yaojun,Ren, Qiao,Wang, Lei,Wang, Jian
supporting information; experimental part, p. 13068 - 13071 (2011/02/21)
Efficient excess: An efficient and facile enantioselective Michael addition reaction through hydrogen-bonding catalysis for the synthesis of coumarin complexes has been developed (see scheme). A simple bifunctional amine-thiourea small molecule has been discovered to catalyze this process with high yields and high to excellent enantiomeric excesses.