1228453-98-2Relevant academic research and scientific papers
Iridium-catalyzed enantioselective allylic substitution of o -allyl carbamothioates
Xu, Qing-Long,Liu, Wen-Bo,Dai, Li-Xin,You, Shu-Li
, p. 4615 - 4618 (2010)
(Figure presented) With an [Ir(COD)Cl]2/phosphoramidite ligand system, an allylic substitution of O-allyl carbamothioates was developed. The reaction proceeded in the favor of branched products with up to 93:7 branched-to-linear ratio, affording chiral S-allyl carbamothioates with up to 95% ee.
