Journal of Organic Chemistry p. 4615 - 4618 (2010)
Update date:2022-07-29
Topics:
Xu, Qing-Long
Liu, Wen-Bo
Dai, Li-Xin
You, Shu-Li
(Figure presented) With an [Ir(COD)Cl]2/phosphoramidite ligand system, an allylic substitution of O-allyl carbamothioates was developed. The reaction proceeded in the favor of branched products with up to 93:7 branched-to-linear ratio, affording chiral S-allyl carbamothioates with up to 95% ee.
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