1228508-01-7

Basic information

• Product Name: 3-[(2S,5R)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]oct-2-yloxy]-6-benzyloxy-(3R,3aS,6R,6aR)-hexahydrofuro[3,2-b]-furan
• CAS NO: 1228508-01-7
• Molecular Weight: 440.479
• Mol File: 1228508-01-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[(2S,5R)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]oct-2-yloxy]-6-benzyloxy-(3R,3aS,6R,6aR)-hexahydrofuro[3,2-b]-furan(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[(2S,5R)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]oct-2-yloxy]-6-benzyloxy-(3R,3aS,6R,6aR)-hexahydrofuro[3,2-b]-furan(1228508-01-7)
• EPA Substance Registry System: 3-[(2S,5R)-3-phenyl-1,3-diaza-2-phosphabicyclo[3.3.0]oct-2-yloxy]-6-benzyloxy-(3R,3aS,6R,6aR)-hexahydrofuro[3,2-b]-furan(1228508-01-7)

Safety Data

• Hazardous Substances Data: 1228508-01-7(Hazardous Substances Data)

Upstream product

• 6338-36-9 2,5-,O'O-dibenzyl-1,4:3,6-dianhydro-D-mannitole 

Relevant articles and documents

Diastereomeric P*-mono- and P*,P*-bidentate diamidophosphite ligands based on 1,4:3,6-dianhydro-d-mannitol in asymmetric metallocomplex catalysis

Synthesis of diastereomeric mono-and bidentate diamidophosphites bearing P*-stereo-centers and phosphabicyclo[3.3.0]octane backbone and their coordination with rhodium(i) and palladium(ii) are considered. Their use in Rh-catalyzed asymmetric allylation allowed one to achieve 87% ee values and the use in Rh-catalyzed asymmetric hydrogenation gave up to 98% ee.