1228600-99-4

Basic information

• Product Name: S-3,3'-bis(3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol
• Synonyms: S-3,3'-bis(3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol;(S)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]- 5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol, 98%e.e.
• CAS NO: 1228600-99-4
• Molecular Formula: C36H26F12O2
• Molecular Weight: 718.57
• Mol File: 1228600-99-4.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: S-3,3'-bis(3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol(CAS DataBase Reference)
• NIST Chemistry Reference: S-3,3'-bis(3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol(1228600-99-4)
• EPA Substance Registry System: S-3,3'-bis(3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol(1228600-99-4)

Safety Data

• Hazardous Substances Data: 1228600-99-4(Hazardous Substances Data)

Usage

General Description

S-3,3'-bis(3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol, also known as bisphenol A (BPA), is a synthetic compound that is widely used in the production of polycarbonate plastics and epoxy resins. It is a key ingredient in many consumer products such as food and beverage containers, baby bottles, and dental sealants. BPA has been a subject of concern due to its potential estrogenic activity and possible adverse effects on human health, particularly in hormonal and reproductive systems. Research has linked BPA exposure to various health issues, including infertility, obesity, and cancer. As a result, there has been a movement to replace BPA with safer alternatives in consumer products.

Upstream product

• 78229-12-6 (Ra)-3,3’-dibromo-2,2’-dimethoxy-5,5’,6,6’,7,7’,8,8’-octahydro-1,1’-binaphthalene 
• 73852-19-4 3,5-bis-trifluromethylphenylboronic acid 

Relevant articles and documents

The development of the asymmetric Morita-Baylis-Hillman reaction catalyzed by chiral Bronsted acids

This report describes the development of a chiral Bronsted acid-catalyzed asymmetric Morita-Baylis-Hillman (MBH) reaction of cyclohexenone with aldehydes. During the course of our studies on chiral Lewis acid-promoted MBH reactions, we discovered that chi

Synthesis and structural aspects of N-triflylphosphoramides and their calcium salts'highly acidic and effective Bronsted acids

Recently, 1,1′-bi-2-naphthol (BINOL)-based N-triflylphosphoramides emerged as a new class of potent Bronsted acid catalysts. In this paper we describe the efficient synthesis of various BINOL-based N- triflylphosphoramides and their calcium salts. Furthermore, X-ray crystal structure analysis combined with energy-dispersive X-ray spectroscopy (EDX) measurements confirmed that the synthesised chiral N-triflylphosphoramides are highly acidic metal-free catalysts. Freedom! The synthesis and structure determination of various 1,1′-bi-2-naphthol (BINOL)-based N-triflylphosphoramides and their corresponding calcium salts is presented. A simple acidic treatment of the calcium salts provides the metal-free Bronsted acids (see scheme; Tf=trifluoromethanesulfonyl).

A convenient protocol for the synthesis of axially chiral Br?nsted acids

Partially hydrogenated binaphthol monophosphoric acids were prepared via an improved four-step sequence. It is demonstrated that typical protection and deprotection of the phenolic groups are dispensable. The vinyl-substituted derivative has been polymerized to give a novel polymerized organocatalyst.