1228682-63-0

Upstream product

• 455-13-0 4-Iodobenzotrifluoride 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 100-52-7 benzaldehyde 
• 705-31-7 4-trifluoromethylphenylacetylene 

Downstream Products

• 1388624-58-5 (4E)-4-benzylidene-3-phenyl-1-[4-(trifluoromethyl)phenyl]azetidin-2-one 
• 1388624-38-1 benzaldehyde O-{1-phenyl-3-[4-(trifluoromethyl)phenyl]prop-2-yn-1-yl}oxime 
• 1311378-38-7 (E)-4-(trifluoromethyl)benzaldehyde O-[1-phenyl-3-(4-(trifluoromethyl)phenyl)prop-2-yn-1-yl]oxime 
• 1311378-52-5 (E)-3-benzylidene-2,4-bis(4-(trifluoromethyl)phenyl)-2,3-dihydroazete 1-oxide 
• 1228682-68-5 C₁₆H₁₂F₃NO 
• 1567388-32-2 methyl 5-benzyl-2-(trifluoromethyl)-4-(4-(trifluoromethyl)phenyl)furan-3-carboxylate 

Relevant academic research and scientific papers

NaH mediated isomerisation-allylation reaction of 1,3-substituted propenols

A base mediated isomerisation-allylation protocol of 1,3-disubstituted propenols has been established. The use of diaryl and aryl-silyl substrates is reported alongside the use of substituted allyl bromides. Mechanistic experiments have also been conducted to elucidate the reaction pathway. The Royal Society of Chemistry 2013.

Ynones Merge Activation/Conjugate Addition of Chalcogenoborates ArE-Bpin (E=Se, S)

The "pull-push" effect of the Bpin moiety in ArE-Bpin reagents (E=Se, S) is demonstrated by the Lewis acid interaction with the carbonyl group of ynones and the concomitant delivery of ArSe or ArS to the electron-deficient alkyne with impressive stereosel

Synthesis of phosphine-ligated zinc acetylide dimers: Enhanced reactivity in carbonyl additions

Phosphine-ligated dinuclear zinc acetylides effectively promote the alkynylation of carbonyl derivatives. Good to excellent yields (46-91%) of the corresponding propargylic alcohols were obtained from a wide range of substrates. Crystallographic evidence