122875-32-5Relevant academic research and scientific papers
α-C-H Alkylation of Methyl Sulfides with Alkenes by a Scandium Catalyst
Luo, Yong,Ma, Yuanhong,Hou, Zhaomin
, p. 114 - 117 (2018)
The C - H addition of sulfides to alkenes is an atom-efficient route for the functionalization and modification of sulfide compounds through C - C bond formation, but this transformation is highly challenging. We report here the regioselective α-C(sp3) - H addition of a wide range of methyl sulfides to a variety of olefins and dienes by a half-sandwich scandium catalyst. This protocol provides a unique route for the synthesis of diverse sulfide derivatives through C - C bond formation at a sulfur-adjacent carbon atom in a 100% atom efficient fashion.
Lewis Acid Induced Nucleophilic Substitution Reaction of β-Nitro Sulfides
Kamimura, Akio,Sasatani, Hiroyuki,Hashimoto, Toshihiro,Ono, Noboru
, p. 4998 - 5003 (2007/10/02)
The nitro group of β-nitro sulfides is readily substituted by an allyl or a cyano group or hydrogen on treatment with allyltrimethylsilane, cyanotrimethylsilane, or triethylsilane in the presence of an appropriate Lewis acid.The intramolecular Friedel-Cra
