122902-13-0Relevant articles and documents
Reversal of ?-Facial Diastereoselection upon Electronegative Substitution of the Substrate and the Reagent
Cieplak, Andrzej S.,Tait, Bradley D.,Johnson, Carl R.
, p. 8447 - 8462 (2007/10/02)
Electonegative substitution at C-3 of cyclohexanone and methylenecyclohexane is found to increase the relative proportion of axial attack in a number of reactions widely differing from the points of view of the transition-state polarization, geometry, and