99495-15-5Relevant articles and documents
Enantioselective Conjugate Addition of Stabilized Arylzinc Iodide to Enones: an Improved Protocol of the Hayashi Reaction
Casotti, Gianluca,Rositano, Vincenzo,Iuliano, Anna
, p. 1126 - 1131 (2020/12/17)
Stabilised arylzinc iodide, prepared by direct insertion of zinc into aryl iodides, were used as nucleophiles in the Hayashi Rh-catalysed enantioselective conjugate addition to enones. The reaction conditions were optimized in the addition of phenylzinc i
The synthesis method of one-carbon ring expansion of cycloketone dericatives from β-selenyl cycloketone dericatives
-
Paragraph 0041; 0044-0048; 0050-0054, (2020/09/08)
The present invention relates to a method for preparing a cyclic ketone derivative with an increased carbon number by performing a ring expansion reaction of a β-selenyl cyclic ketone derivative. The present invention was first developed by performing the
Anthranilamide (aam)-substituted arylboranes in direct carbon-carbon bond-forming reactions
Kamio, Shintaro,Kageyuki, Ikuo,Osaka, Itaru,Yoshida, Hiroto
supporting information, p. 2624 - 2627 (2019/03/05)
Anthranilamide (aam)-substituted arylboranes, which were reported to serve as masked boranes in the Suzuki-Miyaura coupling, have been found to be directly cross-coupled just by use of an aqueous medium. The excellent stability of 2-pyridyl-B(aam) toward protodeborylation allowed their smooth cross-coupling.