1229239-06-8Relevant academic research and scientific papers
Efficient and enantioselective kinetic resolution of cyclic β-hydroxy sulfides by chiral 1,2-diamine catalyzed asymmetric acylation
Kawamata, Yoshiyuki,Oriyama, Takeshi
experimental part, p. 382 - 384 (2010/07/06)
Kinetic resolution of cyclic β-hydroxy sulfides has been achieved by reaction with benzoyl chloride in the presence of a catalytic amount (0.1 mol %) of a chiral 1,2-diamine combined with triethylamine. This reaction affords the corresponding benzoates and unreacted alcohols with excellent enantioselectivities.
