122934-48-9Relevant academic research and scientific papers
ENANTIOSELECTIVE SYNTHESIS OF SEC-ALLYLALCOHOLS BY CATALYTIC ASYMMETRIC ADDITION OF DIVINYLZINC TO ALDEHYDES.
Oppolzer, Wolfgang,Radinov, Rumen N.
, p. 5645 - 5648 (1988)
Readily available chiral tridentate ligand 8 catalyzes the highly Si-face selective addition of diethyl-, di-n-propylzinc and, more significantly, of divinylzinc to aromatic and aliphatic aldehydes whereas bidentate ligands 11 and 12 exert a topologically reversed catalytic bias.
Enantioselective addition of diethylzinc to aldehydes catalyzed by (1R,2R)-10-(dialkylamino)isoborneols
Hari, Yoshiyuki,Aoyama, Toyohiko
, p. 583 - 587 (2007/10/03)
(1R,2R)-10-Dialkylammoisoborneols, γ-amino alcohol-type ligands, were synthesized from (+)-ketopinic acid. Their catalytic ability as a chiral ligand for enantioselective addition of diethylzinc to aldehydes was evaluated. Among them, the ligand with a 9-
