Tetrahedron Letters p. 5645 - 5648 (1988)
Update date:2022-08-04
Topics:
Oppolzer, Wolfgang
Radinov, Rumen N.
Readily available chiral tridentate ligand 8 catalyzes the highly Si-face selective addition of diethyl-, di-n-propylzinc and, more significantly, of divinylzinc to aromatic and aliphatic aldehydes whereas bidentate ligands 11 and 12 exert a topologically reversed catalytic bias.
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